Heterolysis

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Heterolysis is a chemical process in which a molecule splits into two fragments, each retaining one of the originally bonded electrons. This process is also known as heterolytic fission. Heterolysis is a fundamental concept in organic chemistry and plays a crucial role in many chemical reactions, particularly in the formation of ions.

Mechanism[edit | edit source]

In heterolysis, a bond between two atoms breaks unevenly, resulting in the formation of a cation and an anion. The atom that retains both bonding electrons becomes negatively charged (anion), while the atom that loses both bonding electrons becomes positively charged (cation). This process can be represented as follows:

AB → A⁺ + B⁻

Here, AB is the original molecule, A⁺ is the cation, and B⁻ is the anion.

Factors Influencing Heterolysis[edit | edit source]

Several factors influence the likelihood and rate of heterolysis, including:

  • **Bond Strength**: Weaker bonds are more likely to undergo heterolysis.
  • **Solvent Effects**: Polar solvents can stabilize the ions formed during heterolysis, making the process more favorable.
  • **Electronegativity**: The difference in electronegativity between the two atoms in the bond can affect the distribution of electrons upon bond cleavage.
  • **Temperature**: Higher temperatures can provide the necessary energy to overcome the bond dissociation energy.

Applications[edit | edit source]

Heterolysis is important in various chemical reactions, including:

Comparison with Homolysis[edit | edit source]

Heterolysis should be contrasted with homolysis, where a bond breaks evenly, and each atom retains one of the bonding electrons, resulting in the formation of two radicals. Homolysis is common in reactions involving free radicals.

Related Concepts[edit | edit source]

See Also[edit | edit source]

References[edit | edit source]

External Links[edit | edit source]

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