Astatine

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Decay Chain(4n+1, Neptunium Series)

Astatine is a chemical element with the symbol At and atomic number 85. It is the rarest naturally occurring element in the Earth's crust, occurring only as the decay product of various heavier elements. All of its isotopes are radioactive; the most stable is astatine-210, with a half-life of 8.1 hours. A member of the halogen group, astatine is a metalloid that exhibits characteristics of both metals and non-metals. Due to its extreme rarity and radioactivity, astatine has no significant commercial application and is used only in research.

Properties[edit | edit source]

Astatine is a halogen, occupying group 17 of the periodic table, below iodine. It shares many chemical properties with other halogens but also exhibits some metallic characteristics, making it a metalloid. It is less reactive than iodine and is the least reactive of the halogens. The physical properties of astatine are not well-known due to its rarity and radioactivity, but it is believed to be a solid at room temperature.

Occurrence[edit | edit source]

Astatine is extremely rare, with much less than 1 gram present in the Earth's crust at any given time. It is produced naturally as a decay product of heavier elements, such as uranium and thorium, through the decay chains. These decay chains produce astatine isotopes with very short half-lives, contributing to its scarcity.

Isotopes[edit | edit source]

There are about 39 known isotopes of astatine, with atomic masses ranging from 191 to 229. Astatine-210 is the most stable isotope, with a half-life of 8.1 hours. The isotopes of astatine are all radioactive and decay into isotopes of polonium, radon, bismuth, and lead.

Synthesis[edit | edit source]

Astatine can be synthesized by bombarding bismuth with alpha particles. This process produces astatine-211, an isotope that has been used in some experimental cancer treatments due to its ability to emit alpha particles, which can kill cancer cells.

Uses[edit | edit source]

Due to its radioactivity and scarcity, astatine has no significant commercial uses. Its most notable application is in research, particularly in the field of nuclear medicine, where astatine-211 is used in experimental treatments for certain types of cancer. Astatine's ability to target and destroy cancer cells while minimizing damage to surrounding healthy tissue makes it a subject of ongoing medical research.

Safety[edit | edit source]

Astatine is highly radioactive, and its handling requires strict safety precautions to avoid radiation exposure. Due to its short half-life and the small amounts produced, the risk it poses is limited to direct handling in laboratory settings.


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Contributors: Prab R. Tumpati, MD