Chlorine monofluoride

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Carbonyl-chlorofluoride-2D.png

Chlorine monofluoride is a chemical compound with the formula ClF. It is a colorless gas at room temperature and pressure, known for its extreme reactivity and ability to form compounds with most elements. Chlorine monofluoride is an interhalogen compound, a group of compounds formed between halogens.

Properties[edit | edit source]

Chlorine monofluoride is characterized by its strong oxidizing properties. It reacts with most organic and inorganic substances, often violently. The compound is soluble in solvents such as carbon tetrachloride and anhydrous sulfuric acid, where it can be stored or transported with less risk.

Synthesis[edit | edit source]

Chlorine monofluoride can be synthesized by the direct combination of chlorine and fluorine gases at elevated temperatures. The reaction is highly exothermic and must be conducted with caution to prevent uncontrolled explosions.

Reactivity[edit | edit source]

Due to its high reactivity, ClF is used in a variety of chemical syntheses. It acts as a fluorinating agent, capable of introducing fluorine atoms into organic and inorganic molecules. Its reactivity with water and other hydrogen-containing compounds is particularly notable, often resulting in the liberation of hydrogen fluoride.

Applications[edit | edit source]

Chlorine monofluoride's applications are primarily in the chemical industry, where its potent oxidizing and fluorinating properties are utilized. It is used in the production of fluorinated organic compounds, in the purification of uranium, and as a component in rocket fuels and propellants due to its ability to produce high thrust.

Safety[edit | edit source]

Handling chlorine monofluoride requires strict safety precautions due to its extreme reactivity and toxicity. Exposure can lead to severe chemical burns and respiratory issues. Appropriate protective equipment and procedures are essential when working with this compound.

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Contributors: Prab R. Tumpati, MD