Diacetyl peroxide

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Diacetyl peroxide

Diacetyl Peroxide is a chemical compound with the formula (CH3CO)2O2. It is classified as an organic peroxide, a group of compounds that contain a peroxy bond (-O-O-) between two carbon atoms. Diacetyl peroxide is used primarily as a polymerization initiator in the manufacture of polymers and as a bleaching agent in the food and cosmetics industries.

Properties[edit | edit source]

Diacetyl peroxide is a colorless, crystalline solid at room temperature. It is soluble in organic solvents but has limited solubility in water. This compound is sensitive to heat, friction, and impact, which can cause it to decompose explosively. Therefore, it is usually handled and stored with care, under specific conditions that minimize the risk of decomposition.

Applications[edit | edit source]

Polymerization Initiator[edit | edit source]

In the plastics industry, diacetyl peroxide serves as an initiator for the polymerization of monomers into polymers. It is particularly useful in the production of polyvinyl chloride (PVC) and other vinyl polymers. The peroxide decomposes to generate free radicals, which then initiate the polymerization process.

Bleaching Agent[edit | edit source]

Diacetyl peroxide is employed as a bleaching agent in the preparation of flour, fats, oils, and waxes. It is also used in the cosmetics industry for bleaching hair and teeth whitening products. The bleaching action is due to the compound's ability to decompose and generate oxygen radicals, which can break down colored compounds.

Safety[edit | edit source]

Handling diacetyl peroxide requires caution due to its explosive potential when subjected to heat, shock, or friction. It is also a strong oxidizing agent, capable of causing fires upon contact with combustible materials. Safety measures include storing the compound in a cool, dry place away from sources of ignition and handling it with protective equipment. In the event of decomposition, diacetyl peroxide can release acetic acid and oxygen, which are irritants to the skin, eyes, and respiratory system.

Regulation[edit | edit source]

Due to its hazardous nature, the use and handling of diacetyl peroxide are regulated by various health and safety guidelines. These regulations ensure that workers are protected from the potential risks associated with exposure to this compound and that measures are in place to prevent accidental decomposition.

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Contributors: Prab R. Tumpati, MD