Lithium azide

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Lithium azide
Lithium-azide-2D.png
Structural formula of lithium azide
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Lithium azide is an inorganic compound with the chemical formula LiN₃. It is the lithium salt of hydrazoic acid and is composed of lithium cations (Li⁺) and azide anions (N₃⁻). Lithium azide is a white crystalline solid that is highly sensitive to shock and friction, making it a compound of interest in the field of explosive materials.

Structure and Properties[edit | edit source]

Lithium azide crystallizes in a hexagonal structure similar to that of sodium azide. The azide ion (N₃⁻) is linear and symmetric, with a bond angle of 180 degrees. The compound is highly soluble in water and decomposes upon heating to release nitrogen gas, a property that is characteristic of azides.

Synthesis[edit | edit source]

Lithium azide can be synthesized by the reaction of lithium hydroxide (LiOH) with hydrazoic acid (HN₃):

LiOH + HN₃ → LiN₃ + H₂O

This reaction must be carried out with caution due to the explosive nature of hydrazoic acid and the sensitivity of lithium azide.

Applications[edit | edit source]

Lithium azide is primarily used in the field of pyrotechnics and propellants. Its ability to rapidly decompose and release nitrogen gas makes it useful in applications where a rapid expansion of gas is required. However, due to its sensitivity, it is less commonly used than other azides such as sodium azide.

Safety and Handling[edit | edit source]

Lithium azide is a hazardous material that must be handled with extreme care. It is sensitive to shock, friction, and static electricity, and can detonate under certain conditions. Proper protective equipment and protocols must be followed when working with this compound.

Also see[edit | edit source]

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Contributors: Prab R. Tumpati, MD