Methanol

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Cativa-process-catalytic-cycle

Methanol, also known as methyl alcohol amongst other names, is a chemical with the formula CH3OH (often abbreviated MeOH). It is the simplest alcohol, and is a light, volatile, colorless, flammable liquid with a distinctive odor very similar to, but slightly sweeter than, ethanol (drinking alcohol). Methanol is used in various industrial applications, primarily as a solvent, fuel, and antifreeze, as well as a feedstock for the production of formaldehyde, acetic acid, and a variety of other chemicals.

Production[edit | edit source]

Methanol is produced primarily through the catalytic hydrogenation of carbon monoxide. The most common process involves the use of a mixture of carbon monoxide and hydrogen gases in the presence of a catalyst under high pressure and temperature. This method, known as the Methanol to Olefins (MTO) process, is a key component in the production of synthetic hydrocarbons and plastics. Another significant method of methanol production involves the gasification of biomass to produce syngas, which is then converted into methanol, making it a renewable resource for chemical feedstock.

Uses[edit | edit source]

Methanol has a wide range of uses in various industries. It is a popular solvent due to its ability to dissolve both polar and nonpolar compounds, making it invaluable in the pharmaceutical, paint, and plastics industries. As a fuel, methanol can be used directly in internal combustion engines or as a precursor to produce biodiesel via transesterification. It is also used in fuel cells, particularly direct methanol fuel cells (DMFCs), which hold promise for the future of clean energy. In addition, methanol serves as an antifreeze in pipelines and windshield washer fluid, and as a denaturant for ethanol.

Health and Safety[edit | edit source]

Methanol is toxic to humans, and ingestion, inhalation, or prolonged skin contact can lead to methanol poisoning. Symptoms of exposure include headache, dizziness, nausea, lack of coordination, and in severe cases, blindness and death. Treatment for methanol poisoning typically involves the administration of ethanol or fomepizole, both of which act as competitive inhibitors of the enzyme alcohol dehydrogenase, thereby reducing the metabolism of methanol to its toxic metabolites, formaldehyde, and formic acid.

Environmental Impact[edit | edit source]

While methanol is biodegradable and has a lower environmental impact compared to many other solvents and fuels, its production and use still pose environmental risks. The release of methanol into the environment can lead to the contamination of water sources, and its combustion as a fuel produces carbon dioxide, a greenhouse gas. However, when produced from biomass, methanol can be considered a more sustainable and less environmentally damaging option compared to fossil fuels.

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Contributors: Prab R. Tumpati, MD