Noble metal

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Noble metals are a group of metals that are resistant to corrosion and oxidation in moist air, unlike most base metals. The term is often used in a relative sense to denote metals that have superior resistance to corrosion and oxidation, compared to other metals. This group traditionally includes metals such as gold, silver, and the platinum group metals: platinum, palladium, rhodium, ruthenium, iridium, and osmium. These metals are considered "noble" because they stand out due to their rarity in the earth's crust, their economic value, and their chemical properties, particularly their resistance to corrosion.

Properties and Uses[edit | edit source]

Noble metals are highly sought after due to their chemical stability, which makes them resistant to corrosion, oxidation, and acid attacks, except for aqua regia, a mixture of nitric and hydrochloric acid, which can dissolve gold and platinum. Their resistance to corrosion is a key factor that makes these metals ideal for use in high-end jewelry, electrical contacts, and connectors. For instance, gold's excellent conductivity and resistance to tarnishing make it valuable for electronic components.

The platinum group metals, due to their catalytic properties, find extensive use in automotive catalytic converters, which help reduce harmful emissions. Platinum, in particular, is used in various chemical processes as a catalyst, including the production of nitric acid and the refining of crude oil.

Economic and Historical Significance[edit | edit source]

Historically, noble metals have played a significant role in economic systems as currency and store of value. Gold and silver, for example, have been used to mint coins and as standards for monetary systems in many cultures. Their scarcity and the difficulty in extracting them from the earth have contributed to their high value.

In modern times, the value of noble metals continues to be high due to their uses in industry, technology, and jewelry. The market for these metals is global, with prices fluctuating based on demand, mining supply, and geopolitical factors.

Chemical Characteristics[edit | edit source]

Noble metals are characterized by their filled d electron bands, which contribute to their low reactivity. Their resistance to corrosion and oxidation is due to the formation of a passivation layer, which is a surface layer of oxide that protects the metal underneath from further corrosion. This property is particularly notable in platinum and gold, which do not oxidize at all in air, even at high temperatures.

Environmental and Health Considerations[edit | edit source]

While noble metals are invaluable in various applications, their mining and refining processes can have significant environmental impacts. The extraction of these metals often involves mining activities that can lead to habitat destruction, water pollution, and other environmental harms. Additionally, the refining processes can release toxic substances into the environment.

From a health perspective, noble metals are generally considered to be of low toxicity. However, certain compounds containing noble metals, particularly those used in industrial applications, can pose health risks if not handled properly.

Conclusion[edit | edit source]

Noble metals, with their unique properties and wide range of applications, continue to be of great importance in modern society. Their resistance to corrosion, catalytic properties, and historical significance as mediums of economic exchange underscore their value. Despite their benefits, it is essential to consider the environmental and health impacts associated with their extraction and use.

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Contributors: Prab R. Tumpati, MD