Pentachlorobenzene

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Pentachlorobenzene[edit | edit source]

Structural formula of pentachlorobenzene

Pentachlorobenzene is an organochlorine compound with the chemical formula C_HCl_. It is a derivative of benzene in which five of the hydrogen atoms are replaced by chlorine atoms. This compound is a colorless solid that is used in various industrial applications.

Chemical Properties[edit | edit source]

Pentachlorobenzene is a stable compound under normal conditions. It is poorly soluble in water but soluble in organic solvents such as benzene, toluene, and chloroform. The presence of multiple chlorine atoms makes it a persistent organic pollutant.

Structure[edit | edit source]

The structure of pentachlorobenzene consists of a benzene ring with five chlorine atoms attached. The chlorine atoms are positioned symmetrically around the ring, which contributes to the compound's stability and low reactivity.

Production[edit | edit source]

Pentachlorobenzene is produced as a byproduct in the manufacture of polychlorinated biphenyls (PCBs) and other chlorinated compounds. It can also be synthesized by the chlorination of benzene or chlorobenzene under controlled conditions.

Uses[edit | edit source]

Pentachlorobenzene has been used in the past as a fungicide and flame retardant. However, due to its environmental persistence and potential health effects, its use has been restricted in many countries.

Environmental Impact[edit | edit source]

Pentachlorobenzene molecule

Pentachlorobenzene is classified as a persistent organic pollutant (POP) under the Stockholm Convention. It can accumulate in the environment and in the tissues of living organisms, leading to potential ecological and health risks. It is resistant to degradation and can be transported over long distances in the atmosphere.

Health Effects[edit | edit source]

Exposure to pentachlorobenzene can occur through inhalation, ingestion, or skin contact. It is considered to be toxic, with potential effects on the liver, kidneys, and nervous system. Long-term exposure may lead to more serious health issues, including cancer.

Regulation[edit | edit source]

Due to its persistence and toxicity, the use and production of pentachlorobenzene are regulated under international agreements such as the Stockholm Convention. Many countries have implemented measures to reduce or eliminate its release into the environment.

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Contributors: Prab R. Tumpati, MD