Pentamethylcyclopentadiene

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Pentamethylcyclopentadiene is a chemical compound with the formula C10H16. It is a colorless liquid that is used as a ligand in organometallic chemistry.

Structure and bonding[edit | edit source]

Pentamethylcyclopentadiene is a cyclopentadiene derivative, and like other cyclopentadienes, it is aromatic. It has a five-membered ring structure, with each carbon atom bonded to two other carbon atoms and two hydrogen atoms. The carbon atoms are also bonded to each other by a double bond, which contributes to the compound's aromaticity.

Synthesis[edit | edit source]

Pentamethylcyclopentadiene can be synthesized from cyclopentadiene by a process known as methylation. This involves the addition of a methyl group to the cyclopentadiene molecule. The methylation process can be carried out using a variety of reagents, including methyl iodide and dimethyl sulfate.

Applications[edit | edit source]

In organometallic chemistry, pentamethylcyclopentadiene is used as a ligand. A ligand is a molecule that binds to a central metal atom to form a coordination complex. Pentamethylcyclopentadiene is particularly useful as a ligand because it can bind to a wide range of metal atoms, including transition metals and lanthanides.

Safety[edit | edit source]

Like many chemical compounds, pentamethylcyclopentadiene should be handled with care. It can cause skin and eye irritation, and it is harmful if swallowed or inhaled. Appropriate safety measures should be taken when handling this compound, including the use of protective clothing and eye protection.


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Contributors: Prab R. Tumpati, MD