Calcium carbonate

Calcite

Calcite+Aragonite

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Calcite+Vaterite

Silfurberg

Calcium carbonate chunks

Calcium carbonate is a chemical compound with the formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite (most notably as limestone, which contains both of those minerals) and is the main component of pearls and the shells of marine organisms, snails, and eggs. Calcium carbonate is the active ingredient in agricultural lime and is created when calcium ions in hard water react with carbonate ions to create limescale. It is medicinally used as a calcium supplement or as an antacid, but excessive consumption can be hazardous.

Chemistry

Calcium carbonate occurs in two crystal forms: hexagonal β-Calcite and orthorhombic Aragonite. Calcite is the most stable and abundant form of calcium carbonate, with aragonite changing to calcite at 380-470°C. When exposed to acid, calcium carbonate releases carbon dioxide (CO2) through the reaction CaCO3 + 2H+ → Ca2+ + CO2 + H2O, making it a key ingredient in the manufacture of soda ash and as a CO2 source in the chemical industry.

Production

Calcium carbonate is produced either by grinding, crushing, and screening natural sources of limestone, chalk, and marble, or synthetically by the precipitation of calcium carbonate from calcium oxide. The precipitation process allows for the production of high-purity calcium carbonate, which is used in a wide range of applications.

Applications

Industrial

In the industrial sector, calcium carbonate is used as a filler in concrete, increasing its durability and appearance and helping to reduce costs. It is also used in the production of cement, plastics, rubber, and paints, acting as a filler to add strength and durability to the final product.

Agricultural

In agriculture, calcium carbonate is used to neutralize acidic soils and provide a source of calcium for plants. It is also used in animal feed as a calcium supplement.

Medical

Medically, calcium carbonate is used as an antacid to relieve heartburn, acid indigestion, and upset stomach. It is also used as a dietary calcium supplement in individuals who do not get enough calcium from their diets.

Environmental

Calcium carbonate plays a crucial role in water treatment and purification by neutralizing acidic conditions in both soil and water. It is also used in the sequestration of carbon dioxide in the atmosphere, contributing to the reduction of greenhouse gas emissions.

Environmental Impact

While calcium carbonate is generally considered safe for the environment, the mining and processing activities associated with its production can lead to land degradation, habitat destruction, and pollution. Sustainable mining practices and the recycling of calcium carbonate-rich materials are essential to minimize its environmental impact.

Health and Safety

Calcium carbonate is generally recognized as safe when used in moderation. However, excessive intake can lead to hypercalcemia, characterized by nausea, vomiting, confusion, and other symptoms. Inhalation of calcium carbonate dust can cause respiratory issues.