Spherulite
A spherulite is a spherical aggregate of radiating crystals, often found in geological and polymeric contexts. These structures can form in a variety of materials, including volcanic glass, certain minerals, and synthetic polymers, where they affect the material's properties and behavior.
In geology, spherulites are commonly observed in volcanic glasses, where they form through the rapid cooling of silica-rich lava. These geological spherulites can vary in size from microscopic to several meters in diameter. The radiating crystal pattern is often composed of feldspar or quartz, and the presence of spherulites in volcanic glass can influence its fracture patterns and physical properties.
In the field of polymer science, spherulites are important in understanding the crystallization behavior of polymers. They form when a polymer crystallizes from the melt, organizing into a spherical structure composed of radiating crystalline lamellae. The size, shape, and internal structure of polymer spherulites can significantly affect the material's optical and mechanical properties, such as transparency, strength, and toughness. The study of spherulites in polymers is crucial for the development of materials with desired characteristics for applications in plastics, fibers, and films.
The formation of spherulites is influenced by various factors, including the cooling rate, the presence of impurities or nucleating agents, and the molecular structure of the material. Understanding these factors allows scientists and engineers to control the properties of materials by manipulating their spherulitic structure.
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Contributors: Prab R. Tumpati, MD