Enthalpy change of solution

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Enthalpy Change of Solution

The enthalpy change of solution (ΔH_sol) is the enthalpy change associated with the dissolution of a solute in a solvent to form a solution. It is a specific type of enthalpy change and is a crucial concept in thermodynamics and physical chemistry.

Definition[edit | edit source]

The enthalpy change of solution is defined as the amount of heat absorbed or released when one mole of a solute dissolves in a specified amount of solvent. This process can either be endothermic (absorbing heat) or exothermic (releasing heat), depending on the nature of the solute and solvent involved.

Calculation[edit | edit source]

The enthalpy change of solution can be calculated using the following steps:

1. Lattice Enthalpy (ΔH_lattice): The energy required to break the ionic bonds in the solute. 2. Hydration Enthalpy (ΔH_hydration): The energy released when the ions are surrounded by water molecules.

The overall enthalpy change of solution is given by:

ΔH_sol = ΔH_lattice + ΔH_hydration

Factors Affecting Enthalpy Change of Solution[edit | edit source]

Several factors can influence the enthalpy change of solution, including:

  • Nature of the Solute and Solvent: Different substances have different lattice and hydration enthalpies.
  • Temperature: The solubility and enthalpy change can vary with temperature.
  • Pressure: For gases, pressure can significantly affect solubility and enthalpy change.

Applications[edit | edit source]

Understanding the enthalpy change of solution is essential in various fields such as:

Related Concepts[edit | edit source]

See Also[edit | edit source]

References[edit | edit source]

External Links[edit | edit source]

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