Mothball

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White coloured mothball (naphthalene ball) 20230315 180901
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A packet of white coloured mothball (naphthalene ball) 20230315 180612

Mothballs are small balls of chemical pesticide and deodorant used to protect clothes from mold, mildew, and moths, especially when storing clothing and other articles susceptible to damage from these pests. They are also used to protect against similar damage from rodents. The chemicals in mothballs sublimate, meaning they transition from a solid state directly to a gas, which produces fumes that are toxic to moths and their larvae.

Composition[edit | edit source]

Mothballs are made of either naphthalene or paradichlorobenzene, both of which are solid at room temperature and produce strong fumes as they evaporate into the air. Naphthalene is a white, volatile, solid polycyclic hydrocarbon with a strong smell. It is derived from coal tar or petroleum distillation. Paradichlorobenzene, on the other hand, is a less volatile and less flammable compound than naphthalene and has largely replaced it in mothball production due to its lower flammability and toxicity.

Usage[edit | edit source]

To use mothballs effectively, they should be placed in airtight containers along with the items to be protected. This confinement helps to ensure that the fumes build up to a concentration high enough to kill or repel pests. It is important to follow the manufacturer's instructions carefully to avoid risks to human health and the environment. Mothballs should not be used in open spaces or in ways not specified by the product label, as the chemicals they release can be harmful if inhaled or ingested.

Health Risks[edit | edit source]

Exposure to mothball fumes can pose significant health risks, especially to children and pets who may be more sensitive to the chemicals. Symptoms of exposure include headache, nausea, dizziness, and irritation of the eyes and respiratory tract. In severe cases, exposure to naphthalene can cause hemolytic anemia, particularly in individuals with a genetic condition known as G6PD deficiency. Paradichlorobenzene has been linked to liver and kidney damage with long-term exposure.

Environmental Impact[edit | edit source]

Both naphthalene and paradichlorobenzene can cause environmental harm. They are toxic to wildlife, especially in aquatic environments, and can contaminate soil and water. Proper disposal of mothballs is crucial to minimize their environmental impact. They should never be disposed of in open environments but rather according to local hazardous waste management guidelines.

Alternatives[edit | edit source]

Due to the health and environmental risks associated with traditional mothballs, many people seek safer alternatives. These include cedar wood, lavender sachets, and other natural products that repel moths without the use of harmful chemicals. While these alternatives may be safer for humans and the environment, their effectiveness compared to traditional mothballs can vary.

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Contributors: Prab R. Tumpati, MD